Design of new asymmetric reactions and their synthetic applications: i. Asymmetric catalysis ii. Asymmetric carbonyl additions iii. Natural products synthesis
학력
(PhD) 1983. 9. ? 1987. 10. Chemistry, University of California, Davis, CA 95616, USA
약력/경력
1987. 10. ? 1989. 10. Postdoctoral Fellow, Chemistry, Harvard University, Cambridge, MA 02138, USA
1989. 11. ? 1993. 2. Senior Research Scientist, Korea Research Institute of Chemical Technology (KRICT), Daejeon, Korea
1993. 3. ? present Associate Professor, and then Professor, Chemistry, Sungkyunkwan University, Suwon 16419, Korea
2005. 1. ? 2008. 12. Associate Editor, Bulletin of the Korean Chemical Society
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A Regulation of Regiodivergent Routes for Enantioselective Aldol Addition of 2-Alkyl Allenoates with Aldehydes: alpha-Addition versus gamma-Addition.
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Enantioselective Synthesis of a Furan Lignan (+)-Sylvone.
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Synthesis and anti-tubercular activity of 2-nitroimidazooxazines with modification at the C-7 position as PA-824 analogs.
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Asymmetric Aldol Reaction of Allenoates: Regulation for the Selective Formation of Isomeric Allenyl or Alkynyl Aldol Adduct.
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Regulation of Diastereoselectivity in the Carbocyclization of Allenyl (S)-N-tert-Butylsulfinimines through a Three-component Assembly.
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Regulation of Diastereoselectivity in the Carbocyclization of Allenyl (S)-N-tert-Butylsulfinimines through a Three-Component Assembly.
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A Convenient Method for the Synthesis of Allenoates from 4-Hydroxyalk-2-ynoates with PPh3.
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A Convenient Method for the Synthesis of Allenoates from 4-Hydroxyalk-2-ynoates with PPh3.
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An Intramolecular Cyclocarbonylation of Allenyl Sulfinimides by Molybdenum Carbonyl for the Synthesis of Bicyclic 3-Methylene-1-pyrrol-2-ones.
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A novel allylic transfer reaction of chirally modified 2-borylbutadiene: synthesis of chiral homoallenyl alcohols.
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A new allylic transfer reaction of chirally modified 2-borylbutadiene with aldehydes.
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Intramolecular Carbocyclization of Allenoate-aldehydes with Hexamethylditin Catalyzed by Palladium Complex: Synthesis of Cyclic Dienes.
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Intramolecular Carbocyclization of Allenoate-aldehydes with Hexamethylditin Catalyzed by Palladium Complex: Synthesis of Cyclic Dienes.
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Asymmetric Sequential Allylic Transfer Strategy for the Synthesis of (–)-Adaline and (–)-Euphococcinine.
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Efficient Synthesis of Dibenzo[a,c]cyclohepten-5-ones via a Sequantial Suzuki-Miyaura Coupling and Aldol Condensation Reaction.
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Stereoselective Cylization of Allenoates Containing Carbonyl Functionalities Mediated Mo(CO)6: Synthesis of Canadensolide and Sporothriolide.
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Asymmetric Seuqential Allylic Transfer Strategy for the Synthesis of (-)-Aldaline.
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Stereoselective Cyclization of Allenoates Containing Carbonyl Functionalities Mediated by Mo(CO)6.
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Regulation of Cyclization for the Stereoselective Synthesis of Substituted Tetrahydrofurans and Tetrahydrooxepines.
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A diastereoselective carbocyclisation of allene-hydrazones through the intramolecular allylic transfer reaction.
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특허/프로그램
신규 염소-함유 알릴전이시약 및 이를 이용한 비닐클로로하이드린 및 비닐옥시란의 입체선택적.
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학술회의논문
(2018)
A Conversion of erythro-5-(1-hydroxyakyl)-furan-2(5H)-ones to threo- Diastereomers under Basic Epimerization Conditions.
122nd General Meeting of the Korean Chemical Society.
대한민국
(2018)
A Highly Effective Kinetic Differentiation of Racemic Aldehydes by Allenoate Aldol Reaction: Correction of Stereochemistry for (+)- Xylogiblactone A.
122nd General Meeting of the Korean Chemical Society.
대한민국
(2018)
Loreclezole as a new class of potent insect growth regulators with mosquitocidal activity.
122nd General Meeting of the Korean Chemical Society.
대한민국
(2018)
A Highly Efficient Allenoate Aldol Reaction with Racemic Aldehydes through Kinetic Resolution: Synthesis of (+)-Xylogiblactone A.
121st General Meeting of the Korean Chemical Society.
대한민국
(2018)
A Highly Efficient Asymmetric Gamma Carbonyl Addition Reaction of 2-Alkylallenoates: Toward a Synthesis of (+)-Phellilane D.
121st General Meeting of the Korean Chemical Society.
대한민국
(2015)
Governing Factors for Gamma-Selective Route for Asymmetric Aldol Reaction of Allenoates and Their Synthetic Applications.
제116회 대한화학회 학술발표회.
대한민국
(2015)
Diverse New Asymmetric Routes of Allenoates through Carbonyl Additions and Their Synthetic Applications.
IUPAC 45th World Chemistry Congress.
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(2015)
Regulation of Stereochemical Routes for Asymmetric Aldol Reaction of Allenoates: Governing Factors and Applications.
제115회 대학화학회 학술발표회.
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Stereochemical Conversion from anti-Vinyl chlorohydrins to syn-Vinyl chlorohydrin via trans Vinyl oxyranes.
제115회 대학화학회학술발표회.
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(2014)
Cloroallylic Transfer Reactions for the Enantio- and Diastereoselective Synthesis of 3-Vinyloxiranes: Enantioselective Synthesis of Ponticaepoxide.
제114회 대학화학회 학술발표회.
대한민국
(2014)
Regulation for the Formation of Isomeric Allenyl or Propargylic Aldol Adducts from Aldol Reaction of Allenoates: Concise Synthesis of (+)-Sylvone.
제114회 대학화학회 학술발표회.
대한민국
(2014)
A Construction of Center and Axis Chirality through Aldol Reaction of Allenoates: Formation of Unprecedented Gamma Addition Products.
제113회 대학화학회 학술발표회.
대한민국
(2014)
A New Carbocyclization of Allenyl-glyoxylates via Palladium Catalysis through Three-component Assembly: Synthesis of Cyclopinol.
제113회 대학화학회 학술발표회.
대한민국
(2013)
A Highly Stereoselective Aldol Reaction of Allenoates with Aldehydes for the Synthesis of threo 3-Butynoate Aldol Adduct.
대한화학회 제112회 학술발표회.
대한민국
(2013)
Chloroallylic Transfer Reactions for the Enantio- and Diastereoselective Synthesis of 3-Vinyloxiranes: Synthesis of Annuadiepoxide.
대한화학회 제112회 학술발표회.
대한민국
(2013)
Dearomatizative Cyclization of Vinyl Oxiranes through Fridel-Crafts Type Reaction by Lewis Acid Catalysis.
대한화학회 제111회 학술발표회.
대한민국
(2013)
Highly Diastereo- and enantioselective Aldol Reaction of Allenoates with Aldehydes for the Synthesis of Alkynyl Aldol Adduct.
대한화학회 제111회 학술발표회.
대한민국
(2012)
Highly Stereoselective Aldol Reaction of Allenoates with Aldehydes for the Synthesis of Alkynyl Aldol Adduct.
대한화학회 제110회 학술발표회.
대한민국
(2012)
A Highly Stereoselective Fridel-Crafts Type Cyclization of Trans- and Cis Vinyl oxiranes via Lewis Acid Catalysis.
대한화학회 제110회 학술발표회.
대한민국
(2012)
Stereoselective Aldol Reaction of Allenoates and Their Synthetic Applications.
The 6th Kansai-CMDS Meeting on OMCOS, 2012.
대한민국
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